Available in MS Word (.doc) and Adobe Acrobat Reader (.pdf) formats, there's an excellent set of guides for download that documents the full range of PowerShell cmdlets available for working with Windows Azure services. The cmdlets, themselves, are all available in the Windows Azure Pack for Windows Server.
Each doc lists out the available cmdlets per topic and then hotlinks each cmdlet to a location in the document where you can read full information. The docs are huge. The Administrative doc sits at 217 pages by itself.
The documents available cover the following areas:
- SQL Server
- Web sites
You can grab one or all here: Cmdlet Reference Download for Windows Azure Pack for Windows Server